Well-defined indium(III)N-heterocyclic carbene complexes with triflate ligands: structural models for the In(OTf)3 catalyst.

نویسندگان

  • Jamie H Cotgreave
  • David Colclough
  • Gabriele Kociok-Köhn
  • Giuseppe Ruggiero
  • Christopher G Frost
  • Andrew S Weller
چکیده

Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.

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عنوان ژورنال:
  • Dalton transactions

دوره 10  شماره 

صفحات  -

تاریخ انتشار 2004